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The interaction of glucose oxidase (GOD) and four photosensitizers, ZnpcS4,ZnPc(NHCH2COOH)4, CIAIPcS, and porphyrine-like, were monitored by capillaryelectrophoresis. GOD, its degenerated products and photosensitizers were simultaneouslyseparated in a buffer of 300 mmol/L borate at PH 8.5 on a commercial CE instrument. Bycomparison of the electropherograms of GOD as well as the mixture of GOD and photosensitizerswithout/with irradiation of different time, it was found that photosensitized oxidationsbetween GOD and different photosensitizers have different reaction mechanisms and kinetics.
The interaction of glucose oxidase (GOD) and four photosensitizers, ZnpcS4, ZnPc (NHCH2COOH) 4, CIAIPcS, and porphyrine-like, were monitored by capillary electrophoresis. GOD, its degenerated products and photosensitizers were simultaneously stimulated in a buffer of 300 mmol / L borate at PH 8.5 on a commercial CE instrument. By comparison of the electrogramsograms of GOD as well as the mixture of GOD and photosensitizerswithout / with irradiation of different time, it was found that photosensitized oxidationsbetween GOD and different photosensitizers have different reaction mechanisms and kinetics.