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本文对合成的1-氧-4,7,10-三氮杂环十二烷和它的含钯加合物进行了元素、红外、核磁、质谱和热分析;并对加合物做了单晶结构测试。加合物晶体属正交晶系,空间群为P2_12_12_1;晶胞参数为a=10.474(2),b=11.632(2),c=14.674(3),AZ=4。结构的偏离因子R=0.052。加合物中,钯(Ⅱ)与四个氯形成平面四边形配位,以H_2PdCl_4分子存在,冠醚环上的一个N原子与HCl的H~+结合形成铵鎓离子,分子式为NHC_2H_4OC_2H_4N H_2C_2H_4NHC_2H_4C1·H_2PdC1_4·H_20.
The synthesis of 1-oxo-4,7,10-triazacyclododecane and its palladium-containing adducts were investigated by elemental, infrared, nuclear magnetic resonance, mass spectrometry and thermal analysis. The adduct was mono Crystal structure test. The adduct crystals are orthorhombic with space group P2_12_12_1; unit cell parameters are a = 10.474 (2), b = 11.632 (2), c = 14.674 (3), AZ = 4. The structure of the deviation factor R = 0.052. Adduct, Palladium (Ⅱ) and four chlorine form a square tetragonal complex with H_2PdCl_4 molecule exists, a crown ether ring and the H atom of H ~ + combine to form ammonium cation, the formula is NHC_2H_4OC_2H_4N H_2C_2H_4NHC_2H_4C1 · H_2PdC1_4 · H_20.