Stereoselective Addition of N-Alkylhydroxylamines to α,β-Unsaturated Nitro Compounds

来源 :中国化学快报（英文版） | 被引量 : 0次 | 上传用户：yueyingz4l

【摘要】

：

N-Alkylhydroxylamines have been shown to undergo a stereospecific cis addition to 1-phenyl-2 -nitropropene compounds, whereas the corresponding O-alkylhydroxyla

【作者】

：

Ai Jun LI Ji Cheng CHU Hong Sh

【机构】

：

School of Chemical Engineering and Technology,Medical College

【出处】

：

中国化学快报（英文版）

【发表日期】

：

2004年期

【关键词】

：

N-Alkylhydroxylamines O-alkylhydroxylamines concerted addition mechanism α β-uns

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N-Alkylhydroxylamines have been shown to undergo a stereospecific cis addition to 1-phenyl-2 -nitropropene compounds, whereas the corresponding O-alkylhydroxylamines give no diastereoselectivity. The concerted addition mechanism was provided to explain the difference.

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Stereoselective Addition of N-Alkylhydroxylamines to α,β-Unsaturated Nitro Compounds

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