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A new organic-inorganic hybrid coordinated polymer [Zn(C8H23N5)]2(Pb3I10) (C8H23N5 = tetraethylene pentamine) was synthesized by hydrothermal reaction. It crystallizes in triclinic, space group P1 with a = 9.781(2), b = 11.442(3), c = 11.565(3) ?, α = 99.075(8), β = 90.540(9), γ = 109.967(5)o, Zn2C16H46N10Pb3I10, Mr = 2399.94, V = 1198.4(5) ?3, Z = 1, Dc = 3.325 g/cm3, F(000) = 1048.0, μ(MoKα) = 17.951 mm-1, the final R = 0.0412 and wR = 0.0993 for 3375 observed reflections with I > 2σ(I). The title compound consists of [Zn(C8H23N5)]2+ cations and anionic chains [Pb3I10]n4n-, which are combined with each other via electrostatic attractive forces and N–H…I hydrogen bonds.
It crystallizes in triclinic space group P1 with a = 9.781 (2), b = 11.442 (b) 3, c = 11.565 (3) ?,? = 99.075 (8),? = 90.540 (9),? = 109.967 (5) o and Zn2C16H46N10Pb3I10, Mr = 2399.94 and V = 1198.4? 1 with Dc = 3.325 g / cm3, F (000) = 1048.0, μ (MoKα) = 17.951 mm-1, the final R = 0.0412 and wR = 0.0993 for 3375 observed reflections with I> 2σ (I) consists of [Zn (C8H23N5)] 2+ cations and anionic chains [Pb3I10] n4n-, which are combined with each other via electrostatic attractive forces and N-H ... I hydrogen bonds.