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本文研究了电子轰击、化学电离条件下四碘合钴酸十八胺、四氯合钴酸十八胺加热分解产生的C_(18)H_(37)NH_3~+(m/z270)离子碰撞诱导解离谱,在低碰撞能量范围(0～10eV)、多次碰撞条件下观察到了远电荷碎裂反应,给出了反应所需内能的估计值,该离子比直接由正十八胺质子化得到的离子具有较高的内能。
In this paper, the C_ (18) H_ (37) NH_3 ~ + (m / z270) ion collisions induced by thermal decomposition of octadecylaminetetraiodocobaltate and octadecylaminetetrachlorocobaltate under electron bombardment and chemical ionization conditions were studied. The spectra of dissociation were dissociated, the far charge fragmentation reaction was observed under the conditions of low collision energy (0 ~ 10eV) and multiple collisions, and the estimated internal energy required for the reaction was given. The ion ratio was directly protonated by n-octadecylamine The resulting ions have a higher internal energy.