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<正>The six multiimidazole copper(Ⅰ)complexes are utilized to mimic tyrosinase.The main product is 3,5-di-t-butylcatechol from o-hydroxylation of the substrate 2,4-di-t-butylphenol.The highest yield of catechol is up to 82.2% and selectivity 94.8% by