Mechanism for nucleation and growth of electrochemical deposi- tion of palladium（II） on a platinum e

• 作 者: GU Shuai WANG XinPeng WEI YueZ
• 机 构: SchoolofNuclearScienceandEngineering,DepartmentofChemical&,BiologicalEngineering
• 出 处: 中国科学：化学英文版
• 发表日期: 2014年5期
• 关键词: 电化学沉积 盐酸溶液 钯电极 铂电极 成核 电沉积机理 机制 扩散控制 complexes electrodeposition cyclic voltamm
• 基金项目: This work was supported by the National Natural Science Foundation of China （91026019, 91126006）.

Palladium(II)and chloride ions tend to form complexes in aqueous solution.Both theoretical and experimental(by UV spectrum)results indicate that there are four complexes formed in aqueous solution containing 3 mol/L hydrochloric acid and 20mmol/L PdCl2.Th