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合成了 7种草酸根桥联的 Cu 2 Fe 、Ni 2 Fe 、Co 2 Fe 异三核配合物 [M2 Fe(C2 O4) 3Lx](Cl O4) ,(M=Cu,L=bpy,Me2 phen,NO2 phen,x=2 ;M=Ni,Co,L=bpy,Me2 phen,x=4 ) .经元素分析、摩尔电导和磁性的测定以及红外光谱和电子光谱等方法对这些配合物进行了表征 ,确定了配合物的组成和结构 .初步生物活性试验表明形成异三核配合物后其杀菌活性明显提高
Seven oxalate-bridged Cu 2 Fe, Ni 2 Fe and Co 2 Fe heterotriplexes [M 2 Cu (C 2 O 4) 3Lx] (Cl O 4) , NO2 phen, x = 2; M = Ni, Co, L = bpy, Me2 phen, x = 4). These complexes were characterized by elemental analysis, molar conductance and magnetic measurements, infrared spectroscopy and electron spectroscopy Characterization, to determine the composition and structure of the complex.A preliminary biological activity test showed that the formation of heterotrimer complex after its bactericidal activity was significantly improved