Hydrothermal Synthesis and Crystal Structure of a Novel Catena Co（ Ⅱ ） Complex Bridged by Biphenyl-2

• 作 者: MIAOQian HUMao-lin LIXin-hua X
• 机 构: SchoolofChemistryandMaterialsScience
• 出 处: 高等学校化学研究：英文版
• 发表日期: 2005年3期
• 关键词: 热液合成方法 晶体结构 钴 联苯-2 2'-乙二酸盐 阴离子 聚合物 Cobalt(Ⅱ) complex Biphenyl-2 2′-dicarbox
• 基金项目: Support by the Instrument Analysis Fund of Zhejiang Province，the Zhejiang Provincial Technology Project Foundation of China

The title complex, [Co2(bpdc)2(bim)4]n(bpdc=biphenyl-2,2'-dicarboxylate dianion, bim=benzimidazole), was synthesized in a aqueous solution and its crystal structure was determined by means of X-ray diffraction. There are two different coordinated Co(Ⅱ