【摘 要】
：
Doping and coating are frequently employed for the improvement of the properties of Ni-rich NCM materials.In this work,we prepared stable LiNi0.8Co0.1Mn0.1O2 (NCM811) materials modified with Y2O3 via a wet chemical method.In order to investigate the actio
【机 构】
：
Institute of Energy Resources,Hebei Academy of Science,Shijiazhuang 050081,China;Hebei Engineer Rese
论文部分内容阅读
Doping and coating are frequently employed for the improvement of the properties of Ni-rich NCM materials.In this work,we prepared stable LiNi0.8Co0.1Mn0.1O2 (NCM811) materials modified with Y2O3 via a wet chemical method.In order to investigate the action mechanism of Y2O3 on NCM811,we analyzed the microstructures using X-ray diffraction (XRD),X-ray photoelectron spectroscopy (XPS),scanning electron microscopy (SEM),and transmission electron microscopy (TEM).Also,to study the electrochemical performances,we conducted a charge/discharge test and cyclic voltammetry.Our results show that Y2O3 modified NCM811 materials have good thermal stability,and proper content of Y2O3 can effectively prevent the materials from damaging and significantly improve the electrochemical proper-ties of the materials.Particularly,1％ Y2O3 modified NCM811 material show much better cycling per-formance than other samples.During cycling at 1.0C,the 1％ Y2O3 modified NCM811 shows capacity retention of 90.1％ after 100 cycles,which is higher than 69.4％ for pristine NMC811.We examined the microstructures of the materials before and after circulation.Using the SEM results,we conclude that structural changes are among the key factors that lead to the degradation of the electrochemical properties of materials.
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