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本文报道了用XeCl准分子激光引发香芹酮(1)化学反应的研究结果.根据反应产物香芹酮樟脑(2)和1-挂,5-二甲基一顺-2-[(乙氧羰基)甲基]双环[2.1.1]己烷(3)与激光照射能量的关系,得出香芹酮的1→2→3的反应过程.实验表明,在低激光强度照射时,每照射1焦耳能量生成2和3的量随着激光强度的增加而增加,并显示出饱和趋势.同时在照射过程中观察到浓度效应和发光.
In this paper, we report the results of the chemical reaction of carvone (1) initiated by XeCl excimer laser.According to the reaction products carvone camphor (2) and 1-linked, 5-dimethyl cis- 2 - [ Carbonyl] methyl] bicyclo [2.1.1] hexane (3) with the energy of laser irradiation to obtain the reaction process of 1 → 2 → 3 of carvone. Experiments show that at low laser intensity irradiation, 1 Joules The amount of energy generation 2 and 3 increased with the increase of laser intensity and showed a tendency of saturation, while the concentration effect and luminescence were observed during the irradiation.