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二茂铁具有独特的夹心刚性结构,炔基具有刚性和线性,茂铁基与炔基的结合使得二茂铁炔基具有两者的优点,成为用途广泛的刚性构筑块,而且茂铁炔基因体系扩展的π-π电子离域产生了分子导线效应。本文介绍了近几年来茂铁炔基在分子导线、分子开关、分子马达、化学传感器、非线性光学材料、催化剂等光电功能材料领域的研究进展。
Ferrocene has a unique sandwich rigid structure, alkynyl has a rigid and linear, ferrocene and alkynyl combination of ferrocene has the advantages of both to become a versatile rigid building block, and the ferrocene gene The system extended π-π electron delocalization produces molecular lead effects. In this paper, the research progress of ferrocene in recent years in molecular fields such as molecular wires, molecular switches, molecular motors, chemical sensors, nonlinear optical materials and catalysts has been introduced.