论文部分内容阅读
用含水稀土钐氯化物SmCl_3·6H_2O和NaS_2CNEt_2·3H_2O反应,然后加入溴化四乙基铵,生成钐配合物[Et_4N][Sm(S_2CNEt_2)_4]黄色晶体。对该配合物的红外光谱、固体反射光谱、X射线光电子能谱和电氧化还原性质进行了详细的研究。
The samarium complex [Et_4N] [Sm (S_2CNEt_2) _4] yellow crystals were obtained by the reaction of SmCl_3 · 6H_2O and Na_2CNEt_2 · 3H_2O with samarium chloride in aqueous solution and then with tetraethylammonium bromide. The infrared spectra, solid state reflectance spectra, X-ray photoelectron spectroscopy and electro-oxidation reduction properties of the complexes were studied in detail.