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[K(C_12H_24O_6)]_2Pd(SCN)_4(H_2O),MT=963.59,monoclinic, P21/n,a= 11. 075(1),b= 12. 231(1),c= 15. 863(2) A ,β=93. 25(1)°,V=2145. 3A3,Z=2, Dc=1. 492gcm-3,λ(MoKa) = 0. 71073A μ=8. 64cm-1,F(000) = 996,final R=0. 045 for 1835 observable reflections. The Pd2+ ion coordinates with four S atoms from SCN- groups forming a regular square planar configuration. The K+ ion is surrounded by six ether oxygen atoms,one O atom from water molecule coordinated to two K+ions and one N atom from SCN- group to form a distorted hexagonal bipyramid. Two K atoms are linked with one Pd atom by two bridging SCN- groups forming a chain molecular array in the crystal.
863 (2) [K (C_12H_24O_6)] _2Pd (SCN) _4 (H_2O), MT = 963.59, monoclinic, P21 / n, a = 11. 075 (1), b = ) A, β = 93.25 (1) °, V = 2145. 3A3, Z = 2, Dc = 1.492gcm-3, λ (MoKa) = 0. 71073A μ = 8.464cm-1, F ) = 996, final R = 0. 045 for 1835 observable reflections. The Pd2 + ion coordinates with four S atoms from SCN- groups forming a regular square planar configuration. The K + ions are surrounded by six ether oxygen atoms, one O atom from water molecule coordinated to two K + ions and one N atom from SCN-group to form a distorted hexagonal bipyramid. Two K atoms are linked with one Pd atom by two bridging SCN-groups forming a chain molecular array in the crystal.