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誘导反应在分析化学中始終是一个极其重要的、尚待解决的問題。因为它是分析化学中(尤其是容量分析)最大誤差来源之一;另一方面,近来利用誘导反应来鉴定和测定一些元素的方法也越来越多。可是,对于誘导反应历程的研究,虽然經过百多年的努力,直到現在还是很不够的。目前,一般都认为誘导反应实际上是誘导中間产物的化学反应;这些高度活泼的,只能瞬时存在的誘导中間产物引起了誘导反应。在本文中,我們企图首先介紹誘导反应中的基本概念,列出常見的誘导反应,井介紹一些在分析化学中被利用的誘导反应,然后讲各种防止誘导反应发生的方法。最后想要根据現在的理論水平,总結誘导反应中一些不很成熟的規律。这样,对今后的研究工作可能会有一点好处的。
Induction reaction in analytical chemistry has always been an extremely important and unresolved issue. Because it is one of the biggest sources of error in analytical chemistry, especially in capacity analysis; on the other hand, there are more and more ways to use induction reactions to identify and determine some elements recently. However, the study of the induction reaction process, though after more than a hundred years of efforts, has not been enough till now. Currently, it is generally accepted that the inducible reaction is actually a chemical reaction that induces the intermediates; these highly reactive, transiently transient, induced intermediates induce an inducible response. In this paper, we attempt to first introduce the basic concepts of inducible reactions, list common induction reactions, introduce some of the induced reactions utilized in analytical chemistry, and then describe various ways to prevent the induction of the reaction. Finally want to summarize some of the less mature rules in the induction reaction based on current theoretical levels. In this way, there may be some benefits to future research.