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十二氢十二硼酸双桥氯四(三苯基膦)合双钯(Ⅱ)是一种新合成的红色粉末状固体,其元素分析测定值与理论值相符,但其拉曼光谱与红外光谱尚未见报道.为了探讨这类配合物的分子结构,我们参照有关文献,测定了它们的拉曼光谱和红外光谱,并对其特征频率进行了初步的归属和指认.
Dodecahydridododecaborate bis-bridged tetrachloro-tetrakis (triphenylphosphine) -palladium (II) is a newly synthesized red powdery solid whose elemental analysis is consistent with the theoretical value, but its Raman spectrum is similar to the infrared In order to investigate the molecular structure of these complexes, we have studied their Raman spectra and infrared spectra with reference to related literatures, and initially assigned and identified their characteristic frequencies.