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用XRD,IR,DTA-TG和X-射线荧光分析方法研究了有机硅试剂CH_3Si(OC_2H_5)_3和NH_2(CH_2)_3Si(OC_2H_5)_3分别嵌入层状α-Zr(HPO_4)_2·H_2O中,在一定温度下灼烧为具有不同层间距的SiO_2交联α_Zr(HPO_4)_2·H_2O。通过吸附正已烷的吸附等温线测定证明SiO_2交联成柱的α-Zr(HPO_4)_2·H_2O是多孔的类沸石材料。
The effects of the organic silicon reagents CH_3Si (OC_2H_5) _3 and NH_2 (CH_2) _3Si (OC_2H_5) _3 on the layered α-Zr (HPO_4) _2 · H_2O were studied by XRD, IR, DTA- At a certain temperature, it was burned into SiO_2 cross-linked α_Zr (HPO_4) _2 · H_2O with different interlayer spacing. The α-Zr (HPO_4) _2 · H_2O with SiO_2 cross-linked into column was proved to be a porous zeolitic material by adsorption isotherms of n-hexane.