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Owing to continuous production lines with large amount of consecutive controls, various control signals and huge logistic relations, this paper introduced the methods and principles of the development of knowledge base in a fault diagnosis expert system that was based on machine learning by the four-layer perceptron neural network. An example was presented. By combining differential function with not differentia function and back propagation of error with back propagation of expectation, the four-layer perceptron neural network was established. And it was good for solving such a bottleneck problem in knowledge acquisition in expert system and enhancing real-time on-line diagnosis. A method of synthetic back propagation was designed, which broke the limit to non-differentiable function in BP neural network.