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Mn4+离子激活的荧光粉在固态照明领域作为红光发射的热点载体正日益受到关注.我们针对当前研究热度撰写了Mn4+离子光谱学的回顾,并在回顾中聚焦了许多对红色荧光粉商业研制有价值的重要基础研究点.这些研究点涵盖了如何理解自由和晶场状态下Mn4+离子的能级结构以及Mn4+发射波长对基质的依赖关系.此外,我们就如何实验调控Mn4+离子掺杂型荧光粉的发射波长和发光强度给出了许多实际可行的建议.更为重要的是,我们收集并讨论了100多种荧光粉基质中Mn4+离子光谱学参数,对它们的理解将会为未来Mn4+掺杂型红色荧光粉的实验开发奠定基础.“,”Phosphors activated with Mn4+ ion are gaining prominence in the field of solid-state lighting as generators of red photon. In the present review, we focus on several important points that are fundamentally important to produce a com-mercially useful phosphor. This includes an understanding of the Mn4+ energy levels in the free state and in the crystal fields and of the host dependent variations in the Mn4+ emission wavelength. Additionally, we formulate several practical recommendations on how to tune the emission wavelength and emission intensity of Mn4+-doped phosphors. The main spec-troscopic parameters of the Mn4+ ion in more than 100 phosphor materials are collected and discussed.