Synthesis, Structure and Photoluminescence of One Zinc-based Metal-metallosalen Framework

• 作 者: ZHU Cheng-Feng BAN Feng-Jun SH
• 机 构: CollegeofChemistryandMaterialsScience,ChinaTobacco,SchoolofChemistryandChemicalTechnologyandStateKey
• 出 处: 结构化学
• 发表日期: 2013年2期
• 关键词: 分子网络结构 光致发光 锌配合物 合成 X-射线晶体学 二维配位聚合物 框架 金属 crystal structure salen coordination
• 基金项目: This work was supported by NSFC-21025103 and 20971085, ＂973＂ Programs （2007CB209701 and 2009CB930403 ）, and Shanghai Science and Technology Committee （10DJ1400100） and the key project of State Educati

<正>Dicarboxyl-functionalized salen ligand 1,2-phenylendiamine-N,N?-bis(3-tert-butyl- 5- (carboxyl)-salicylide-ene (H_4L) was synthesized in good yield from 3-tert-butyl-5-formyl-4-hy- droxybenzoic acid and used to construct a 2D zinc complex, [(ZnL)