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The objectives of this study were to explore the spatial distribution of soil available microelements and to provide a firm foundation for scientifically formulated fertilizer. 1076 soil samples were collected from Pinggu County of Beijing, China, and the contents of available Cu, Zn, Fe, and Mn in topsoil (0-20 cm) and subsoil (20-40 cm) were analyzed respectively. Descriptive statistics and geostatistics were used to analyze the data. The mean values of topsoil available Cu, Zn, Fe, and Mn were 1.96, 2.51,17.32, and 10.91 mg kg-', respectively, which were at medium or at slightly above medium level. The topsoil content of the soil available microelements was more than that of subsoil. The result of semivariance analysis showed that the topsoil available Fe and Mn were spatially correlated at a larger distance of 21.6 and 45.3 km, and the available Cu and Zn were at a shorter distance of 3.1 and 2.9 km, respectively. The subsoil spatial correlation distances were obviously different from the topsoil, which were in the order of available Mn>Cu>Zn = Fe. The Kriging method was applied to calculate the unobserved points and was used to generate the contour map. The results showed that the structural factors, such as topology, soil types, and soil properties, were the main factors influencing the spatial distribution of topsoil available Fe and Mn. Topsoil available Cu and Zn contents were mainly affected by land use, and their contents in orchard and in vegetable land were greatly higher than in field. The spatial distribution of subsoil microelements was similar to that of the topsoil, which exhibited vertical distribution patterns. Fertilizer and pesticide application resulted in the higher contents of available Cu and Zn in Pinggu County. The higher content of available Zn is potentially harmful to soil environmental quality, which should be inspected.