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本文首次报道了一种新的二氯-二聚吡咯合钯(简称 DCBPP)配合物的合成、结构和吸附 H_2行为的实验和理论研究.确定了 DCBPP 的稳定性结构,探究了吸附过程的表面行为和微观机制,理论计算和实验测定的结果符合较好,圆满合理地说明一些实验现象.
In this paper, the synthesis and structure of a new dichloro-dipolypyrrolyl palladium (abbreviated DCBPP) complex and the experimental study on its adsorption of H 2 have been reported for the first time. The structure of DCBPP has been determined and the surface of the adsorption process has been investigated Behavioral and microscopic mechanisms, theoretical calculations and experimental results in good agreement, a number of experimental phenomena to illustrate fully and reasonably.