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有机碱的氯铈(Ⅳ)酸盐对于四氯化铈的稳定性,存在形式等方面的研究,具有重要的意义。随着这类化合物性质的不断揭露,它们已在无机合成中获得了实际应用。因此,近年来吸引了不少学者,对它们展开了广泛的工作。 本文系统地调研了八十余年近四十篇文献,对R_2CeCl_6和R_4CeCl_8型化合物的合成及其物理化学性质的研究历史和现状,作了概括的介绍。
The study on the stability, existing forms and other aspects of cerium (IV) acid salts of organic bases is of great significance. With the continuous disclosure of the properties of these compounds, they have gained practical applications in inorganic synthesis. Therefore, in recent years, many scholars have been attracted to carry out a wide range of work on them. In this paper, we systematically investigated nearly forty articles in more than eighty years and made a brief introduction to the history and present situation of the synthesis and physicochemical properties of R 2 CeCl 6 and R 4 CeCl 8 compounds.