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Two cyanide bridged trinuclear compounds [Fe(bpy)2(CN)2]·[Cu(Cyclam)]2- (ClO4)4·DMF 1 and [Fe(Phen)2(CN)2]·[Cu(Cyclam)]2(ClO4)4·2CH3CN·4H2O 2 (Bpy = 2,2’- bipyridine, Phen = 1,10-phenanthroline, Cyclam = 1,4,8,11-tetraaza-cyclotetradecane, and DMF = N,N-dimethylformamide) have been synthesized by using mononuclear [Fe(Phen)2(CN)2]·2H2O and [Fe(bpy)2(CN)2]·3H2O as precursors. These two complexes crystallize in monoclinic space groups P21/c and C2/c, respectively. For 1, a = 25.164(2), b = 12.0405(11), c = 20.4433(15) , β = 91.948(3)o, V = 6190.5(9) 3, Z = 4, Mr = 1418.90, Dc = 1.522 g/cm3, F(000) = 2936, μ = 1.161 mm-1, the final R = 0.0722 and wR = 0.2011 for 10779 observed reflections (I > 2σ(I)). For 2, a = 43.5945(0), b = 11.8447(0), c = 29.5637(2), β = 120.430(11)o, V = 13162.76(9) 3, Z = 8, Mr = 1518.48, Dc = 1.533 g/cm3, F(000) = 6288, μ = 1.101 mm-1, the final R = 0.0711 and wR = 0.1783 for 11262 observed reflections (I > 2σ(I)).
Two Cyanide Bridged Trinuclear Compounds [Fe (bpy) 2 (CN) 2] [Cu (Cyclam)] 2- (ClO4) ] 2 (ClO4) 4.2CH3CN.4H2O2 (Bpy = 2,2’-bipyridine, Phen = 1,10- phenanthroline, Cyclam = 1,4,8,11-tetraaza-cyclotetradecane, and DMF = N, N- dimethylformamide have been synthesized by using mononuclear [Fe (Phen) 2 (CN) 2] · 2H2O and [Fe (bpy) 2 (CN) 2] · 3H2O as precursors. These two two-dimensional crystallites in monoclinic space groups P21 / c and C = 20.4433 (15) β, β = 91.948 (3) o, V = 6190.5 (9) 3, Z = 4, Mr = 1418.90, Dc = 1.522 g / cm3, F (000) = 2936, μ = 1.161 mm-1, the final R = 0.0722 and wR = 0.2011 for 10779 observed reflections (I> 2σ (I) A = 43.5945 (0) b = 11.8447 (0) c = 29.5637 (2) β β = 120.430 (11) o V = 13162.76 93 Z = 8 Mr = 1518.48 Dc = 1.533 g / cm3, F (000) = 6288, μ = 1.101 mm-1, the final R = 0.0711 and wR = 0.1783 for 11262 observed reflections (I> 2σ (I)).