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标题化合物采用锌粉、硫粉及 2 甲基吡啶直接反应 ,最后得到金黄色晶体 ,其结构由X 射线结晶学分析得到晶体数据。晶体属单斜晶系 ,空间群Cc,Z =4,Mr=,a =7.5 10 (2 ) ,b =17.2 95 (5 ) ,c=13.6 85 (1) ,β =94.6 0 (1)° ,V =1771.7 3,Dc=1.6 6 g/cm3,μ(MoKα) =2 0 .9cm- 1,F(0 0 0 ) =90 4。利用 2 389个独立观察点修正到R =0 .0 5 1,Rw =0 .0 6 1。标题化合物是 1个中性分子 ,分子中有 1个扭曲ZnS2 N2 四面体核心。
The title compound was directly reacted with zinc powder, sulfur powder and 2 picoline to give a golden yellow crystal. The structure was analyzed by X-ray crystallography to obtain crystal data. The crystals are monoclinic with a space group Cc of Z = 4, Mr =, a = 7.510 (2), b = 17.295 (5), c = 13.685 , V = 1771.7 3, Dc = 1.6 6 g / cm 3, μ (MoKα) = 2.09 cm -1, and F (0 0 0) = 90 4. Using 2 389 independent observation points, we correct R = 0 .0 5 1, Rw = 0 .0 6 1. The title compound is a neutral molecule with 1 twisted ZnS2 N2 tetrahedron core.