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我在苏联列宁格勒大学化学系二年级时,曾在华西里柯娅和马个丁诺娅领导下开始做学年论文。给我的题目是:“制取UOCl_3和测定它的生成热”,同时也指定文献给我看,文献中有许多铀的化合物,可是混合化合物不多,估计可能存在的化合物如UOCl_3,UOCl_2,UOCl等等就根本找不到,这样一来,一方面使我高兴,另一方面却使我感到很空虚。完全由于苏联老师热情的指导和无微不至的关怀,在实验失败时给我打气,使我一直情绪饱满地进行工作。下面谈谈工作的简况。无机合成UOCl_3的反应式是:
When I was in the second grade of chemistry at the Leningrad University in the Soviet Union, I started my academic year thesis under the leadership of Huseyin Koya and Ma Dingnuoya. Give me the title: “Preparation of UOCl_3 and determination of its heat of formation”, but also specify the literature to show me that there are many uranium compounds in the literature, but not many compounds, it is estimated that the possible compounds such as UOCl_3, UOCl_2, UOCl and so on simply can not find, so, on the one hand I am happy, on the other hand it makes me feel empty. Thanks to the enthusiastic guidance and meticulous care of the Soviet Union teachers, I cheer on the failure of the experiment so that I have been working full of emotion. Here to talk about the work of the brief. The reaction of inorganic synthesis UOCl_3 is: