【摘 要】
：
以吡啶-2,6-二甲酸为原料,经过四步反应以中等产率得到了手性吡啶单噁唑啉配体L1～L6.考察了该类新型配体在1,3-二羰基化合物与β-硝基芳基乙烯的不对称Michael加成反应中的手
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以吡啶-2,6-二甲酸为原料,经过四步反应以中等产率得到了手性吡啶单噁唑啉配体L1～L6.考察了该类新型配体在1,3-二羰基化合物与β-硝基芳基乙烯的不对称Michael加成反应中的手性诱导能力.当底物为1-氯-2-（2-硝基）苯乙烯时,在-60℃下以三氯甲烷为溶剂,用L5-Ni（ClO4）2.6H2O作为催化剂,得到了87%产率和68%的对映体过量（ee）值,获得了较好的实验结果,扩大了单噁唑啉配体在不对称合成中的应用.
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