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A new coordination compound,Ni(C6H12N4)2SO4·4H2O(NSH-HMTA)(HMTA,hexamethylenetetramine,C6H12N4),has been synthesized and its single crystals were obtained.NSH-HMTA belongs to the triclinic system,space group P1 with a=9.2534(6),b=13.3131(2),c=16.0373