Quasi-solid state synthesis of EU-1 zeolite and its catalytic properties for the isomerization of C_

来源 :Petroleum Science | 被引量 : 0次 | 上传用户:zhuyudream
下载到本地 , 更方便阅读
声明 : 本文档内容版权归属内容提供方 , 如果您对本文有版权争议 , 可与客服联系进行内容授权或下架
论文部分内容阅读
In this study,EU-1 zeolite was successfully synthesized via a quasi-solid state approach and assembled to catalyst for the C 8 aromatics isomerization process.The catalytic properties were tuned through careful modification of the acidity of EU-1 zeolites and metal-doping of the catalyst.It was shown that EU-1 was an excellent candidate for the C 8 aromatics isomerization process due to its unique structure.In addition,steam treatment of EU-1 at 450-500 ℃ could optimize the acidic properties of the catalyst,hence enhance its catalytic performance.The effect of the amount of Pt on ethylbenzene conversion was studied and the optimum amount was determined to be about 0.3-0.4 wt%.It was confirmed that EU-1 zeolite prepared via a quasi-solid state approach and then dealuminated by steam treatment had better activity and selectivity than conventional mordenite(MOR) zeolite and could be an excellent candidate for C 8 aromatics isomerization. In this study, EU-1 zeolite was successfully synthesized via a quasi-solid state approach and assembled to catalyst for the C 8 aromatics isomerization process. The catalytic properties were tuned through careful modification of the acidity of EU-1 zeolites and metal-doping of the catalyst. It was EU-1 was an excellent candidate for the C 8 aromatics isomerization process due to its unique structure. In addition, steam treatment of EU-1 at 450-500 ° C could optimize the acidic properties of the catalyst , whereby enhance its catalytic performance. The effect of the amount of Pt on ethylbenzene conversion was studied and the optimum amount was determined to be about 0.3-0.4 wt% .It was confirmed that EU-1 zeolite prepared via a quasi-solid state approach and then dealuminated by steam treatment had better activity and selectivity than conventional mordenite (MOR) zeolite and could be an excellent candidate for C8 aromatics isomerization.
其他文献
痛风与痛风性关节炎属于嘌呤(Purine)代谢失调性疾病。在国外,特别是欧美等国家属多见病,欧美各国报告在2—3‰左右,某些地区高达10‰。国内较少,其发病率尚无统计,文献报告
Waldenstr(o|¨)m高丙球蛋白血症紫癜是一种免疫性疾病。自Waldenstr(o|¨)m于1943年首先描述三例女性患者以来,以后续有报道。国内仅张修梅(1964)报道过1例,近来,作者等发
探讨了高职高专化学实验实训教学中的一些方法,包括综合性实验实训课程、角色互换教学、自主性实验实训教学和教学课程范型改革等。 Some methods in the experiment teachi
目的探讨儿产科合作对新生儿窒息及产妇产后出血的积极作用。方法选择1999年10月至2004年9月产科出生的新生儿1866例为对照组;以2004年10月起实施儿产科合作至2009年9月出生
The Pt(Ⅳ) complex cis,cis,trans-[Pt(PMSA)2Cl2(OH)2]2H2O (1), where PMSA=N-3-pyridinylmethanesulfonamide, has been synthesized and characterized by elemental an
为了解学龄前儿童冬季患病情况以便早期干预,笔者于2009年10月1日~2010年1月31日对我院门诊就诊的2943名学龄前儿童进行了为期4个月的专题调查,现将调查结果报道如下。1对象
在北京最顶级的写字楼,建一家充满现代艺术气息的川菜馆,谁会拥有这样的创意?  6年前。一个大胆的女子在北京国贸开了第一家这样的川菜馆,与普遍中低档的川菜料理不同,“俏江南”做工精细,用料讲究,主要面向高端的商务人群。这个女子便是张蓝,俏江南的创始人、俏江南餐饮集团董事会主席。  6年来,张蓝总在做一些大胆到让同行匪夷所思的事,结果证明。她成功了。仅仅几年后,“俏江南”已经成长为在全国拥有20家高档
A simple and sensitive electrochemical detection of caffeine(CAF) using a single-walled carbon nanotubes on carbon-ceramic electrode(SWCNT/CCE) is reported.CAF
In this work,a novel gas phase silent-packed bed hybrid discharge plasma reactor has been proposed,and its ability to control a simulative gas stream containing
在pH 4.0~5.3的条件下,甲砜霉素与溴甲酚绿反应生成具有1个正吸收峰和2个几乎相等的负吸收峰的离子缔合物。最大正吸收波长位于610 nm,2个负吸收波长分别位于652 nm和574 nm,