萜烯低聚物与马来酸酐的加成反应及其制备环氧树脂的研究

• 作 者: 周永红 李英春 王延 宋湛谦
• 机 构: 中国林业科学研究院林产化学工业研究所!江苏南京210042,中国林业科学研究院林产化学工业研究所!江苏南京210042,中国林业科学研究院林产化学工业研究所!江苏南京210042,中国林业科学研究院林
• 出 处: 化学研究与应用
• 发表日期: 2000年03期
• 关键词: 萜烯低聚物 马来酸酐 环氧树脂

Addition reaction of terpene oligomer with maleic anhydride was studied.The suitable conditions were obtained:heterpolyacid H 3[P(W 3O 10 ) 4]·H 2O was used as catalyst;the amount of catalyst used was 1.5% of terpene oligomer (wt.%);the ratio of maleic anhydride and terpene oligomer was 1/1.6～1/1.8(by wt.);reaction temperature was 190±5℃.The epoxy resin was prepared from adduct of oligomer terpene with maleic anhydride.

Addition reaction of terpene oligomer with maleic anhydride was studied. The suitable conditions were obtained: heteropolyacid H 3 [P (W 3 O 10) 4] · H 2 O was used as catalyst; the amount of catalyst used was 1.5% of terpene oligomer ; the ratio of maleic anhydride and terpene oligomer was 1 / 1.6-1 / 1.8 (by wt.); reaction temperature was 190 ± 5 ° C. The epoxy resin was prepared from adduct of oligomer terpene with maleic anhydride.