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活性聚合技术的进步,使设计合成结构可控的含糖聚合物成为可能。本文介绍了阴离子聚合、阳离子聚合、原子转移自由基聚合、可逆加成断裂链转移聚合、硝基氧介导聚合、开环聚合和开环易位聚合等一系列可控/“活性”聚合技术在合成含糖聚合物中的应用,并对这一领域所取得的研究进展及现状进行了综述。
Advances in living polymerization technology make it possible to design sugar-containing polymers with controlled structure synthesis. In this paper, a series of controlled / active properties such as anionic polymerization, cationic polymerization, atom transfer radical polymerization, reversible addition fragmentation chain transfer polymerization, nitroxide mediated polymerization, ring opening polymerization and ring opening metathesis polymerization are introduced. Polymerization technology in the synthesis of sugar-containing polymers, and the progress made in this area and the status quo are reviewed.