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本文以统计热力学的观点，对流动相和固定相同时采用定标粒子理论处理，得到了描述分子间相互作用与ｋ＇间定量关系的关联方程，并对该方程加以实验验证及讨论。
In this paper, statistical thermodynamics, the mobile phase and stationary phase using the same time using the calibration particle theory to obtain the correlation equation describing the quantitative relationship between the intermolecular interaction and k ’, and the experimental verification and discussion of the equation.