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合成了两个含蒽酰亚胺基团的新配体N-(2-(6-氨基吡啶))-9-蒽酰亚胺(L1)和N,N′-(2,6-吡啶基)-二(9-蒽酰亚胺)(L2),以及L1的铜(I)配合物[CuL1(PPh3)2](BF4)(1),并研究了它们的结构和光谱性质.理论计算表明配体L1配位前为反式构象,配合物1的晶体结构显示L1配位后发生结构扭曲呈顺式构象,羰基氧原子与铜(I)离子配位.光谱研究表明配体L1和配合物1都表现出蒽的特征吸收和发射峰.
Two novel anthracene imide group-containing ligands, N- (2- (6-aminopyridine)) - 9-anthracene imide (L1) and N, N ’- ) -bis (9-anthracene imide) (L2) and copper (I) complex [CuL1 (PPh3) 2] (BF4) (1) of L1 were synthesized and their structures and spectral properties were studied. The crystal structure of complex 1 showed that the structure of L1 was coordinated with copper (I) ions and the carbonyl oxygen atom was coordinated with copper (I) ion.The spectral analysis showed that ligand L1 and Complex 1 showed the characteristic absorption and emission peaks of anthracene.