Crystal Structure of Chiral Acetato-bridged Binuclear Cyclopalladated Complex [Pd(μ-O_2CMe)(S-C_6H_4

• 作 者: 杨帆 李一平 聂娟 汤杰 何鸣元
• 机 构: Center for the Chemistry of Ionic Liquids, Department of Chemistry, East China Normal University,Cen
• 出 处: Chinese Journal of Chemistry
• 发表日期: 2003年08期
• 关键词: bridged O_2CMe Pd aromatic chloroform tetra methanol outer

Reaction of ( S) α methylbenzylamine with Pd(OAc) 2 in anhydrous HOAc produced the chiral complex [Pd( μ O 2CMe)( S C 6H 4CHMeNH 2)] 2 (1). The complex was characterized by 1H NMR spectroscopy, elemental analysis and a single crystal X ray analysis. The X ray crystal structure analysis revealed that complex 1 has four isomers: two outer and two inner isomers.

Reaction of (S) α methylbenzylamine with Pd (OAc) 2 in anhydrous HOAc produced the chiral complex [Pd (μ O 2 CMe) (SC 6H 4 CHMeNH 2)] 2 (1). The complex was characterized by 1H NMR spectroscopy, elemental analysis and a single crystal X ray analysis. The X ray crystal structure analysis revealed that complex 1 has four isomers: two outer and two inner isomers.