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本文介绍的络合反应的适宜pH及pH范围的计算方法,能很容易算得金属离子和有机试剂反应的最佳酸度范围,预报实验条件;将计算结果和实验结果对比,还可以确定反应的平衡机理。文中附有Apple Ⅱ微型计算机的BASIC程序及几个络合反应的计算示例。
This article describes the calculation of the appropriate pH and pH range of the complexation reaction, which can easily calculate the optimum acidity range of the reaction between the metal ions and the organic reagent and predict the experimental conditions. By comparing the calculated results with the experimental results, the balance of the reaction can also be determined mechanism. The text attached to the Apple Ⅱ microcomputer BASIC program and several examples of complex reaction calculations.