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对含膦巯基混合物配体的钴化合物Co(SC_6H_5)_2(PBu_3)_2和Co(SC_6H_4CH_3—p)_2(PBu_3)_2的磁极矩和~1H NMR作了实验研究与分析,结果表明:它们均为四面体构型的配合物,其各向同性位移主要来自接触位移的作用。
The magnetic moment and ~ 1H NMR of the cobalt compounds Co (SC_6H_5) _2 (PBu_3) _2 and Co (SC_6H_4CH_3-p) _2 (PBu_3) _2) containing phosphine sulfhydryl mixture were studied and analyzed. The results showed that both For the tetrahedral configuration of the complex, the isotropic displacement mainly from the role of contact displacement.