CRYSTAL STRUCTURE OF FIVE-COORDINATE ZIRCONOCENE COMPLEX CP_2ZrCl(S_2CNBz_2) (Bz=C_6H_5CH_2)

• 出 处: Chinese Chemical Letters
• 发表日期: 1991年11期
• 关键词: bidentate coordinate 八八 一曰 have Silver planar length 月日 S_2CNBz_2

Cp_2ZrCl(S_2CNBz_2) is a five-coordinate bent zirconocene in which the dibenzyldithiocarbamate is a bidentate ligand (Zr-Cl 2.549(1)A; Zr-C 2.489-2.533; Zr-S 2.667(1), 2.734(1); Zr-Cl-S1 137.6(1)~o; Zr-Cl-S2 73.3(1)~o).

Cp 2 ZrCl (S 2 CNBz 2) is a five-coordinate bent zirconocene in which the dibenzyldithiocarbamate is a bidentate ligand (Zr-Cl 2.549 (1) A; Zr-C 2.489-2.533; Zr-S 2.667 -Cl-S1 137.6 (1) ~ o; Zr-Cl-S2 73.3 (1) ~ o).