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首次合了五种Cr(β-dik)Cl_2py_2型(其中β-dik分别为乙酰丙酮、苯甲酰丙酮、三氟乙酰丙酮、2—噻吩甲酰三氟丙酮、二苯甲酰甲烷)和一种Cr(pmbp)Cl_2(thf)混合配体配合物、一种Cr(pmbp)_3配合物。并对上述化合物进行了电子光谱、红外光谱等的表征工作。
For the first time, five kinds of Cr (β-dik) Cl_2py_2 (in which β-dik were acetylacetone, benzoylacetone, trifluoroacetylacetone, 2-thenoyltrifluoroacetone and dibenzoylmethane) Cr (pmbp) Cl_2 (thf) mixed ligand complex, a Cr (pmbp) _3 complex. And the above compounds were characterized by electronic spectroscopy, infrared spectroscopy.