Hydrothermal Syntheses and Crystal Structures of Two Complexes of Cobalt and Manganese Assembled by

• 作 者: 潘亚茹 孙铭 李秀梅
• 机 构: Faculty of Chemistry, Tonghua Normal University,College of Plant Science, Jilin Agriculture Science
• 出 处: 结构化学
• 发表日期: 2015年04期
• 关键词: bonding hydrothermal supramolecular intermolecular stacking benzene complexes ca

Two new coordination polymers [Co(oba)(mbix)]2n·n H2O(1) and [Mn(Hoba)2(H2O)2]n(2)(H2oba = 4,4’-oxydibenzoic acid, mbix = 1,3-bis(imidazol-1-ylmethyl)benzene) have been successfully synthesized under hydrothermal conditions. Their structures have been determined by elemental analyses, IR spectroscopy, UV and single-crystal X-ray diffraction analysis. The intermolecular hydrogen bonding and π-π stacking interactions extend the complexes into a 3D supramolecular structure.

Two new coordination polymers [Co (oba) (mbix)] 2n · n H2O (1) and [Mn (Hoba) 2 (H2O) 2] n (2) (H2oba = 4,4’-oxydibenzoic acid, mbix = , 3-bis (imidazol-1-ylmethyl) benzene) have been successfully synthesized under hydrothermal conditions. Their structures have been determined by elemental analyzes, IR spectroscopy, UV and single-crystal X-ray diffraction analysis. -π stacking interactions extend the complexes into a 3D supramolecular structure.