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Decavanadium oxide [Co2Cl8V10O18(H2O)]Cl2*6H2O was synthesized hydrothermally with NH4VO3, Na2MoO4*2H2O, H3PO4(85%), CoCl2*6H2O and hexamethylenetetraamine. The X-ray diffraction analysis showed that [Co2Cl8V10O18(H2O)]Cl2*6H2O crystallized in a monoclini