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Ultrafast third-order nonlinear optical response of bulk 6H-SiC undoped and doped with different nitrogen concentrations are investigated utilizing fetosecond Z-scan and optical Kerr effect(OKE)techniques at the wavelength of 800 nm.The Z-scan measurement shows that the third-order nonlinear optical susceptibilities of the doped samples are improved in comparison to the intrinsic sample.The 0KE results additionally reveal that the instantaneous nonlinear optical response of the sampies can be ascribed to the distortion of the electron cloud.The ultrafast transient spectroscopic measurements with the one-color and two-color pump-probe techniques demonstrate that the ultrafast recovery process in subpicosecond domain is induced by two-photon absorption process,while the slow relaxation component reflects the carrier dynamics of the excited electrons.