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A numerical wave model based on the modified four-order nonlinear Schrodinger (NLS) equation in deep water is developed to simulate freak waves. A standard split-step, pseudo-spectral method is used to solve NLS equation. The validation of the model is firstly verified, and then the simulation of freak waves is performed by changing sideband conditions. Results show that freak waves entirely consistent with the definition in the evolution of wave trains are obtained. The possible occurrence mechanism of freak waves is discussed and the relevant characteristics are also analyzed.