【摘 要】
：
b Institute of Chemistry, Academia Sinica, Taipei, Taiwan 11529, China One pot hydroiodination and deconjugation of 5 aryloxy(or thiophenyl) 3 pentyn 2
【出 处】
：
Chinese Journal of Chemistry
论文部分内容阅读
b Institute of Chemistry, Academia Sinica, Taipei, Taiwan 11529, China One pot hydroiodination and deconjugation of 5 aryloxy(or thiophenyl) 3 pentyn 2 one with a reagent system of sodium iodide/trimethylsilyl chloride/water in acetonitrile at 25 ℃ have been described. The plausible mechanism was discussed. The reaction provided a simple and useful method for the preparation of ( Z ) β substituted β,γ enones and ( Z ) β substituted α,β unsaturated ketones.
b Institute of Chemistry, Academia Sinica, Taipei, Taiwan 11529, China One pot hydroiodination and deconjugation of 5 aryloxy (or thiophenyl) 3 pentyn 2 one with a reagent system of sodium iodide / trimethylsilyl chloride / water in acetonitrile at 25 ° C have been described The plausible mechanism was discussed. The reaction provided a simple and useful method for the preparation of (Z) β substituted β, γ enones and (Z) β substituted α, β unsaturated ketones.
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