Synthesis and Crystal Structure of a Heterometallic Trinuclear Ni/Ag/S Compound

• 作 者: 靳美亮 马骁 谭春红 沈超君 朱启龙 胡胜民 傅瑞标 盛天录 吴新涛
• 机 构: State Key Laboratory of Structural Chemistry,Fujian Institute of Research on the Structure of Matter
• 出 处: 结构化学
• 发表日期: 2012年01期
• 关键词: structurally silver belongs monoclinic centre inversion oxidized neutral moiety

A new tri-nuclear mixed metal thiolate complex [Ag(PPh3)2]2[Ni(edtO2)2] 1 has been synthesized and structurally characterized by single-crystal diffraction.The molecule has a crystallographic inversion centre occupied in the central Ni(II) atom and the two silver(I) atoms are related by the inversion centre.The unique structural feature is that one of thiolates of each edt ligand has been oxidized to sulfinate from the precursor [Ni(edt)2]2-to the neutral linear trinuclear complex.The crystal structure belongs to the monoclinic system,space group P21/n with a = 13.581(11),b = 12.239(9),c = 22.316(17) ,β = 103.08(2)o,V = 3613(5) 3,Z = 2,Mr = 1571.87,Dc = 1.445 g/cm3,μ = 1.046 mm-1,F(000) = 1604,T = 293(2) K,the final R = 0.0652 and wR = 0.1499 for 6776 observed reflections with I > 2σ(I).

A new tri-nuclear mixed metal thiolate complex [Ag (PPh3) 2] 2 [Ni (edtO2) 2] 1 has been synthesized and structurally characterized by single-crystal diffraction. The molecule has a crystallographic inversion center occupied in central Ni ( II) atom and the two silver (I) atoms are related by the inversion center. The unique structural feature is that one of thiolates of each edt ligand has been oxidized to sulfinate from the precursor [Ni (edt) 2] 2-to the neutral linear trinuclear complex. The crystal structure belongs to the monoclinic system, space group P21 / n with a = 13.581 (11), b = 12.239 (9), c = 22.316 (17) V = 3613 (5) 3, Z = 2, Mr = 1571.87, Dc = 1.445 g / cm3, μ = 1.046 mm- 1, F (000) = 1604, T = 293 0.0652 and wR = 0.1499 for 6776 observed reflections with I> 2σ (I).