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将Fe—M(M=C,SiO2,Al2O3)混合物在Ar中高能球磨56h后测量Mossbauer谱.结果表明,(Fe)2-(SiO2)1仍为Fe和SiO2的机械混合物;(Fe)7-(C)3已完全合金化,生成两种Fe3C;(Fe)2-(Al2O3)1则成为Fe(73%)、尖晶石型的FeAl2O4(22%)、金属Fe的团簇(5%)和Al2O3的混合物.
Mossbauer spectra were measured after high-energy ball milling of Fe-M (M = C, SiO2, Al2O3) for 56 h in Ar. The results show that (Fe) 2- (SiO2) 1 is still a mechanical mixture of Fe and SiO2; (Fe) 7- (C) 3 has been fully alloying to produce two kinds of Fe3C; A mixture of Fe (73%), spinel-type FeAl2O4 (22%), a cluster of metal Fe (5%) and Al2O3.