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金属有机配位聚合物(金属聚合物)由于整合了金属和聚合物的诸多优点而在清洁能源、智能响应材料、高性能器件制备方面具有广泛的应用潜力。本文综述了近十年金属聚合物合成进展,主要从聚合物形成和金属中心引入的顺序,如先合成聚合物再引入金属中心、先合成含金属单体后引发聚合以及一步法合成金属聚合物等方面进行论述,重点介绍合成方法、金属聚合物链结构和性能之间的关系,分析了不同合成方法的优缺点,探讨了金属聚合物合成的研究趋势。
Metal-organic coordination polymers (metal polymers) have a wide range of potential applications in the fields of clean energy, smart response materials, and high performance device fabrication due to the integration of many advantages of metals and polymers. This review summarizes the progress of metal-polymer synthesis in recent ten years, mainly from the order of polymer formation and metal center introduction, such as the first synthesis of polymer and then introduction of metal centers, the first polymerization of metal-containing monomers, and the one-step synthesis of metal polymers And other aspects of the discussion, focusing on the synthesis method, the relationship between the structure and properties of metal polymer chains, analyzed the advantages and disadvantages of different synthesis methods, discussed the metal polymer synthesis research trends.