双(3-对甲苯基-2-硫代咪唑-1-基)-(3-甲基-5-苯基吡唑-1-基)硼氢酸根的镉及钴配合物的合成与结构表征(英文)

• 作 者: 舒谋海 屠春来 崔靖 孙杰
• 机 构: 上海交通大学化学化工学院,上海交通大学化学化工学院,上海交通大学化学化工学院,中国科学院上海有机化学研究所 上海200240,上海200240,上海200240,上海200032
• 出 处: 无机化学学报
• 发表日期: 2006年08期
• 关键词: 三角架配体 结构表征 晶体结构 吡唑 苯基 合成 complexes cadmium polymeric coordinated

Two new complexes CdL2 (1) and CoL2 (2) were synthesized by reactions of L {L =hydrobis(3-p-tolyl-2-thioimidazol-1-yl)-(3-phenyl-5-methyl-pyrazol-1-yl)borate} with cadmium(II) and cobalt(II) acetate respectively, and structurally characterized. The title complexes feature distorted trigonal dipyramidal geometries with a S4H donor set defined by the sulphur and hydrogen atoms of two tripodal sulfur-rich ligands. CCDC: 235514, 1; 244021, 2.

Two new complexes of CdL2 (1) and CoL2 (2) were synthesized by reactions of L {L = hydrobis (3-p-tolyl-2-thioimidazol-1 -yl) -yl) borate} with cadmium (II) and cobalt (II) acetate respectively, and structurally characterized. The title complexes feature distorted trigonal dipyramidal geometries with a S4H donor set by the sulfur and hydrogen atoms of two tripodal sulfur-rich ligands. CCDC: 235514, 1; 244021, 2.