Synthesis and Structural Characterization of a Salt { [Co（Phen）3] [MozSz（μ-S）2（edt）2]}2·（DMSO）2

• 作 者: ZHANGWen-Hua RENZhi-Gang ZHANG
• 机 构: SchoolofChemistryandChemicalEngineering,Suzhou215006
• 出 处: 结构化学
• 发表日期: 2005年7期
• 关键词: and edt terminal with system PHEN atom COCl2 block space group the rise LIGA bon

Reaction of [Et4N]2[Mo2S2(μ-S)2(edt)2] with COCl2·6H2O and Phen in MeCN followed by recrystallization in DMSO/Et2O gave rise to dark-red block crystals of { [Co(Phen)3]-[Mo2g2(μ-S)2(edt)2]}2.(DMSO)2-(Et2O) 1 (C88H86Co2Mo4N12O3S18). 1 crystallizes in