Synthesis of Coordination Polymers Using Different Maleic Acid Ligands under Hydrothermal Condition

• 作 者: WANG Xiao-lan WANG En-bo XU Xi
• 机 构: InstituteofPolyoxometalateChemistry,DepartmentofChemistry
• 出 处: 高等学校化学研究：英文版
• 发表日期: 2007年3期
• 关键词: 马来酸配位体 配位聚合物 合成 水热条件 光致发光 Maleic acid Hydrothermal reaction Mixed ligands Pho
• 基金项目: Supported by the National Natural Science Foundation of China（No. 20371011 ）. Crystallographic data for the structural analysis have been deposited at the Cambridge Crystallographic Data Center. These

A novel coordination polymer, [Ni(mal)(1,10′-phen)(H2O)]n(1)(mal=malate, 1,10′-phen=1,10-phenanthroline) was synthesized using malic acid which was generated from maleic acid via hydrothermal reaction. Complex 1, which displays a two-dimensional supramole