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WC@SnO2 core-shell composite were fabricated by a modified sol-gel method, in which nano-scaled SnO2 particles were uniformly deposited on WC particles modified by PVP(Polyvinylpyrrolidone).And then the Ag/WC@SnO2 contact materials were prepared by a briquette sintering-repressing-re-sintering process.The physical properties, electrical performances and microstructure of as-prepared Ag/SnO2 electrical contacts were investigated.Results show that Ag/SnO2 composites consisting of WC@SnO2 composites have higher density and conductivity.